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It has been observed that there are only a limited number of ways in which the contents of the physical chemistry can be presented to the students. The pedagogical problem is a complex one. The older physical chemistry texts gradually evolved a coherent, integrated presentation in which the student progressed steadily through an accepted sequence of material, with each subject building on the previous one. The attempt here has been to achieve something comparable in the contemporary vein and the present book dealing with Physical Chemistry has been written to meet the requirements of Undergraduate and Postgraduate Students. The stress have been take on making the concepts crystal clear by using simple language, labeled diagrams and precautions. Many modifications have been done in the sub matter on the basis of the observations of my own during the long years of my experience and keeping in mind the difficulties faced by the students in understanding the subject matter.